Oil’s long, dirty, and highly useful fingers

Do you think most acetic acid comes from fermented apples? Think again.

Saudi Arabia is going to cut oil production and although they say they are not doing it for political reasons, we can see our politicians here vocalizing what could be their wishes such as finishing the Keystone pipeline which would bring crude to their refinery in Texas. It’s hard to imagine that some US pols even speak against electric cars made in the USA. Or maybe not. If we all switched immediately to electric vehicles powered by wind and solar energy, would we still need oil? The answer is, yes.

Fuel oil and gas are not the only petroleum based products. The paving and roofing material asphalt is a complicated mixture of large hydrocarbons and plenty of sulfur, vanadium, and nickel impurities and is petroleum based. Tar can be made from coal or found naturally, as in the La Brea Tar Pits in Los Angeles where fossils of mammoths and dire wolves have been found. But tar and asphalt are not the only additional uses for petroleum.

Petroleum is the starting material for most of our plastics and synthetic materials, everything from fibers to pharmaceuticals, starts out as a form of oil.

Hydrocarbons can be chains or rings, and are distinguished by their composition-molecules made from just two elements, carbon and hydrogen. These materials can be light and flammable like naptha and gasoline or heavier as with asphalt and tar. Although they are useful in their own right, organic chemistry can step in and add elements to the hydrocarbons to make them into entirely new compounds. But they are the necessary beginning–the feed stock so to speak.

Here is an example of making something simple, acetic acid, as found in vinegar. Acetic acid contains oxygen in addition to hydrogen and carbon. It can be produced by fermentation as in this reaction where the acetic acid is bolded.

2 CO2 + 4 H2 → CH3COOH + 2 H2O.

It can also be made from alcohol, something you don’t want happening to your wine, for example, in this reaction starting with ethanol (as in wine) and adding oxygen naturally. It’s why you need to carefully control the amount of oxygen when wine making.

C2H5OH + O2 → CH3COOH + H2O

With the proper catalysts, acetic acid can easily be made from oil, for example as in this reaction:

2 C4H10 + 5 O2 → 4 CH3CO2H + 2 H2O

Why would anyone do this when acetic acid can be made from fermentation? We need a lot of it. Non-food acetic acid has been produced industrially since the 1960s and accounts for 90% of the usage world-wide. Over 5 million tons are produced each year. It’s a high demand chemical used to make coatings, paints, inks, and plastics such as PET. It’s one example of how we use chemical feed stock petroleum to make products we use every day.

Twenty percent of each barrel of oil is used as a chemical feed stock and when oil goes up in price, so does anything made from oil.

There are biological ways to make synthetic materials as discussed here and in my novel Lost in Waste. But as long as there is plenty of oil available, it has a long history of being used as a fuel and a feed stock and this isn’t likely to change anytime soon. Kicking the world’s oil addiction won’t be easy, unless we want to go back to life as it was 100 years ago. And we all know how some politicians love plastic bags. Fortunately, crude oil prices are still much lower than their highest point in 2008 so don’t despair. We will have plenty of low cost cigarette butts other plastics in the near future. In fact, the petrochemical industry will no longer be investigated if a plant catches on fire. That’s bad for people who lives near the plants, most on the Gulf Coast, but good for plastic prices.

2024 Science News

2024 science news

Trust in science has fallen, not across the globe but in the US among conservative people This began during the pandemic when people decided to trust their conservative politicians instead of infectious disease experts. Project 2025, the sweeping right-wing blueprint for a new kind of U.S. presidency, will sabotage science-based policies that address climate change, the environment, abortion, health care access, technology and education...and even cancer research. The government funds 40% of basic science, science done to advance knowledge and improve health, and the research is shared with the public and other scientists.  Now, scientific research is on the chopping block.

The US isn’t the only country giving science funding an ill-advised overhaul. New Zeeland is cutting research into social sciences, favoring research into the economy. This raises concerns because this fundamental discipline is an important tool for understanding social cohesion.

Bad news for Boomers and Gen X—the lead from leaded gas probably has made you a little psychotic.

Gun violence is declared a public health crisis.

Consolidation in the fertilizer industry, made worse when Koch Industries bought the taxpayer subsidized Wever Fertilizer plant,

Fructose promotes tumor growth by helping the cancer cells make their outer membranes. Fructose is a simple sugar found in fruits.  Its use in the form of high fructose corn syrup, developed in 1964, has been criticized for causing pollution as well as detrimental health effects such as high cholesterol and obesity. Now we know that it helps promote tumor lipid growth. Lipids are fatty compounds like cholesterol and triglycerides. Lipids make up the membranes around all cells, including cancer cells. Shouldn’t some forms of fructose carry a warning label?

There’s mounting evidence that pesticides, plastics, and other pollutants harm our bones & butterflies & cause heart problems. Are we going to demand more regulations or will we accept our fate?

Getting some new pavement, as I did? It causes 8% of the world carbon emissions. Good news ahead! Climate friendly concrete will soon become available.

Unwashed men pose danger. You may have heard of VOCs, volatile organic compounds, which are released into the air from synthetic products such as carpet, gasoline engines, and paint. These compounds can cause health issues ranging from irritation, headaches, organ damage, and cancer. And, when men don’t wash, they emit them.

Climate change caused 150 billion dollars in damage in 2023, yet few people in the US think they will be affected. Is weather becoming more severe? Yes, it appears so. Hurricane Helene, which washed out a highway I take when I visit my daughter, was an example of heat fueled rain and winds.

Bird flu marches on, with new testing done on milk to ensure safety and track the disease. Pasteurization keeps milk safe. Yet here in Iowa, one of the dirtiest states ever, the bird flu is concentrating and progressing due to lack of any regulations.

Speaking of tests, a blood test to supplement the more invasive colonoscopy has been approved. With colorectal rates skyrocketing, this test should make getting screened easier, although it will not entirely replace colonoscopies.

Plenty of unhealthy synthetic chemicals have been banned this year, including those used in the airline and dry cleaning industries.

The US delayed acting on the Covid -19 virus, setting the vaccine development back. Are you one of those people who think the virus came from a lab? Scientists don’t agree with that.

Humans have predicted eclipses for thousands of years and yet, it’s a pretty tricky calculation. On April 8, many in the US came together to view an Eclipse. Thanks Mother Nature!